The purpose of this study is to examine the effect of female adolescents’ rejection sensitivity, impulsivity and guilt on their binge eating behavior. Questionnaires on rejection sensitivity, impulsivity, guilt and binge eating behavior were administered to 607 female adolescents in Changwon and Ulsan. Of 572 collected copies, 402 were deemed valid and statistically analyzed through frequency analysis, mean and standard deviation, t-test, Pearson’s correlation analysis, multiple regression analysis and stepwise multiple regression analysis using SPSS Win 12.0. The results of the study were as follows: 1) School type was found to make a significant difference in rejection sensitivity, overall impulsivity, guilt and binge eating behavior; however, its influence was not significant on the sub-factors of impulsivity: motor impulsivity, unplanned impulsivity and cognitive impulsivity. 2) For female middle school students, rejection anger sensitivity, rejection depression sensitivity and motor impulsivity were found to have a significant influence on binge eating behavior for both middle school and high school girls. Guilt, however, was found to be influential for female high school students only. 3) Impulsivity was found to have a partial mediating effect on the relationship between female adolescents’ rejection sensitivity and binge eating behavior.